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40.11.6.1.3 Method 3: Synthesis of N,N′-Diarylsulfur Diimides via Amidosulfur Dichlorides

DOI: 10.1055/sos-SD-040-00963

Chemler, S. R.Science of Synthesis, (2009401281.

Symmetrical N,N-diarylsulfur diimides can be synthesized by condensation of arylamines with sulfur tetrafluoride in the presence of triethylamine.[‌64‌] Unsymmetrical N,N-diarylsulfur diimides (e.g., 32) can be synthesized by condensation of arylamines with an appropriate N-arylimidosulfur dichloride (e.g., 31) (Scheme 17).[‌65‌]

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