You are using Science Of Synthesis as a Guest.
Please login to access the full content or check if you have access via40.13 Product Class 13: Ammoniumsulfonates, Thiohydroxylamines, and Aminosulfonium Salts
Please login to access the full content or check if you have access via
Schaumann, E., Science of Synthesis, (2009) 40, 1305.
General Introduction
Amine N-oxides (Section 40.3) may be looked upon as heteroanalogues of N-ylides (see Section 40.1.7); their nitrogen analogues, N-imines, are discussed as part of hydrazine synthesis in Sections 40.7.2.1.5–40.7.2.1.9. The analogous sulfur compounds, amine N-sulfides 1, are not known, though the chemistry of their formal oxidation products, ammoniumsulfonates 2 (Scheme 1), is well documented (see Houben–Weyl, Vol. 11/2, pp 645–682).
Meeeee 8 Meeee M-Meeeeeee eee Meeeeeeeeeeeeeeeee
Meeeee eeee eeeeeeeee ee eeeeeeee eeeeeeeeeeeee eee e eeee eeee, eeeeeeeeeeeeeeeeee eeee eeeeeee eeeeeeeeeee ee eeeeeeeee eeeeeeee ee eeeeeee eeeeeeee 8. Meeeeeeeeee ee eee eeeeeeeeeeee eeeeeeeeeeeee eeeee eeeeeeeeeee 8, eeeee eeeeeeeee ee eeee eee eeeeeeeeeee. Me eeeeeeee, eeeeeeeeeee eeeeeeee eeeeee eeeeeeeeeeee 8 (Meeeee 8).[8]
Meeeee 8 Meeeeeeee ee Meeeeeeeeee eee Meeeeeeeeeee eeee Meeeeee Meeeeeee[8]
M M—M eeee ee eeee eeeeeee ee eeeeeeeeeeeeee eeeee 8 (Meeeee 8). M-Meee eeeeeeeeeee ee eeee eeee eee eeeeeee ee Meeeeee ee Meeeeeeee, Mee. 88e [Meeee—M (M = Mee, M, M, Me, Me) (Meeeeee 88.88.8.8.8)]; eee e eeee eeeeeee eeeeeeeee, eee Meeeee–Meee, Mee. M 88, ee 888–888, 888–888, 8888.
Meeeee 8 Meeeeeeeeeeeee Meeee
Mee eeee eeeeeeeee eeeeeeeeeeeeee eeee ee eeeeeeee(eeeeeeeeeee)eeeeeeeee eeeeeeee (8, eee Meeee–Mee eeeeeee), eeeee ee eeeeeeeee ee eeee eee eeee eee eee eeeeeeeee ee eeeeeeee ee eeeeeeeee eee eeeeeee {eee Meeeeee ee Meeeeeeee, Mee. 88 [Meeeeeeee (Meeeeee 88.8.8.8)]} (Meeeee 8).[8,8]
Meeeee 8 Meeeeeeee eee Meeeeeeeeee ee eee Meeee–Mee Meeeeee[8,8]
Meeeeeeeeee, eee Meeee–Mee eeeeeee ee eeeeee ee eeeeeeee M-eeeeee eeee MM-eeeeee eeeeeeeee ee eeeeeeeeee eeeeee {eee Meeeeee ee Meeeeeeee, Mee. 88 [Meeee Meeeee—Meeeeeeeee Meeee: Meee-, Meeeee-, eee Meeeeeeeeeeeeeeee Meeee eee Meeeeeeeeee; Meeeee Meeee eee Meeeeeeeeee; Meeee Meee Meeeeeeeeee (Meeeeeee 88.8.8.8.8.8 eee 88.8.8.8.8.8.8, eeeeeeeeeeee)]; Mee. 88 [Meeeeee (Meeeeee 88.8.8.8.8.8)]}, ee eeeeeeeeee eeeeeeeeeee {eee Mee. 88 [Meeee Meeeee—Meeeeeeeee Meeee: Meeeeee eee Meeeeeeeeee (Meeeeee 88.88.8.8.8.8)]}, eee eee eee eeeeeeeeeeee ee eeeeeeee {eee Mee. 88 [Meeeeee (Meeeeee 88.8.8.8.8.88)]}. M eeeeeee eeeeeeee eeee ee e eeeeee-eeeeeeee eeeee ee eeeeee {eee Mee. 88 [Meeee Meee-Meeeeeee Meeeeeeee eeee Mee Meeeeeeeee (Meeeeee 88.88.8.8.8.8)]}.
M eeeeeeeeeeeee-eeeeeeeeeee eeeeeeeeeee eeee eeeee eeeeeeeeeeee eeeeeeeee eeee Meeeeee eeeeeeeee eee e eeeeeeeeeee eeeee {eee Meeeeee ee Meeeeeeee, Mee. 88 [Meeeeeeeee Meeeeeeee ee Meeeeeeee eee Meeeeee (Meeeeee 88.8.8.8.888.8.8.8.8)]}.
References
[1] | Meeeee, M. M. M.; Mee, M. M.; Meeeee, M. M., M. Meee. Mee., Meee. Meeeee., (8888), 888. |
[2] | Meeee, M. M.; Mee, M. M., M. Me. Meee. Mee., (8888) 88, 8888. |
[3] | Meeeeeee, M.; Meeeeeee, M.; Meeeeeee, M., Meee. Meeee. Meee., (8888) 88, 8888. |
Meeeeee Meeeeeeeeee
- 8.Meeeee-Meee, (8888) 88/8, 888.
- 8.Meeeee-Meee, (8888) 88/8, 888.
- 8.Meeeee-Meee, (8888) 88/8, 888.