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DOI:
10.1055/sos-SD-041-00002
Aitken, R. A.; Aitken, K. M., Science of Synthesis, (2010) 41, 169.
Poly(methylhydrosiloxane) (PMHS) and phenylsilane are used as the hydride source in the enantioselective reduction of β,β-disubstituted nitroalkenes (Scheme 237).[610] The reactions are carried out in the presence of copper(I) tert-butoxide and the chiral Josiphos {1-[2-(diphenylphosphino)ferrocenyl]ethyldicyclohexylphosphine} ligand.
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References
[610] | Meeeeeeee, M.; Meeeeeee, M. M., Meeee. Meee., (8888) 888, 8888; Meeee. Meee. Mee. Me., (8888) 88, 8888. |