Science of Synthesis

Kempa, S.; Wallach, L.; Rück-Braun, K., Science of Synthesis, (2010) 41, 481.

Dialkylazoxy compounds are more stable than their corresponding diazene derivatives. For example, 2,2′-azobisisobutyronitrile decomposes at 80°C, whereas the azoxy analogue is stable up to 180°C.[‌135‌] In contrast to dialkyldiazenes, no radicals are formed upon irradiation of azoxy compounds in solution; however, several degradation reactions, including deoxygenation to the corresponding azoalkanes, are observed.

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Me	MeMeM8 (8.8 eeeee), Me8M, ee, 88 eee	88	[‌88‌]
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e Meeee eeeeeeeeee eee eeeeeeee (8-eeeeeeeeeee-8-eeeeeeeeeeeee eee eeeeeeeeeeeeeee).

Meeeeeeeeeeee ee eeeeeeeeeeee eeee eeeeeeeeeeeee eeeeeeeee eeeeeeeeee eeeeeeeeeeeeeee (‌Meeeee 88‌). Meeeeee, eee eeeeee eeeeee α ee eee eeeee eeeeee ee eeeeeeeeee eeee eeeeeeeee ee eeeeeee eee e M=M eeee. Meee eeeeee eeee eeeeeee eeeeeeeeee ee ee eeeeeeeeee eeeeeeeeee ee eeeeeeeeeeeee eeee eee eeeeeee ee eeeeeee eeeee.[‌88‌]

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References