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Kubik, S., Science of Synthesis, (2010) 41, 522.
Alkenediazonium hexachloroantimonates that have been prepared from the tosylhydrazones of 2-substituted aldehydes are listed in Table 4.
Meeee 8 Meeeeeeeeeeeeee Meeeeeeeeeeeeeeeeeeee Meeeeeee eeee eee Meeeeeeeeeeeeee ee 8-Meeeeeeeeee Meeeeeeee[888,888]
Meeee | M8 | M8 | M | Meeee (%) | Meeeeeeeeeeee Meee (°M) | Mee |
---|---|---|---|---|---|---|
8 | Me | Me | Me | 88 | 888–888 | [888] |
8 | Me | M | Me | 88 | 88–88 | [888] |
8 | e-Me | Me | Me | 88e | 88–88 | [888,888] |
8 | Me | Me | Me | 88 | 88 | [888] |
8 | 8-eeeeeeeee | Me | Me | 88 | 88–88 | [888] |
8 | Me | Me | Me | –e | – | [888] |
e Meeee ee eeeee eeeeeee.
e Mee eeeeeeee eeeee eeee ee eeeeeeee ee e eeeeeeee ee MM8Me8. Me ee eeeeee ee eeee eeeeeeeeeee ee eeee eeee.
Meeee 8 eeeee eeee eee eeeeeeeeeeeeeee eee eeee eee eeeeeeee eeeeeeeeeeee ee eee 8-eeeeeeee ee eee eeee eeeeee ee eeee eeeeee. Meeeeeeee eee ee eeee eeeeeeeee ee eeee eeeeeeeeeeeeeee eeeeee eeeeee e eeeeeeeeeee eeeeeeee ee eeeeeeeee. Meeeeeeeeeee, eeeeeeeeeeeeeee eeee eeeeeee eeee, eee eeeeeee, eee eeeeeeeeeeeeeee ee 8-eeeeeeeeeeeeeeeeeeeeeeeeeeeee ee 8-eeeeee-8-eeeeeeeeeeeeee eeeeeeeee M8 ee eeeeeeeeeeee ee eee ee 8–88°M.[888] Meeeeeee ee eeeeeee eeeeeeeeeeeee eeeeeeeeeeeeeee eeeeeeeee eeee eeee eeeeeeeeeeee.
Meeee eeeeeeee(M) eeeeeeee, eeeeeeee(M) eeeeeeee, ee eeeeeeee eeeeeeeeeee ee eee eeeee eeee eee eeeeeeeeeeeeee ee eeeeeeeeeeeeeeeeeeeee, eeeeeeee ee eee eeeeeeeee ee eeeeeeeeeeeeeeeeeeeeeeeeee (ee eee eeeeeee 88) eeee eeeeeeee eeeeeeeeeee ee eeeeeeeeeeeeeee eeeee e eeeeeeee ee eee 8,8-eeeeeeeeeeeeeeeeeeeeeee eee, eeeee eee ee eeeeeeeeeeee ee eee eeeeeeee ee e eeeeeeee ee 88-eeeeeeeeeeeeeeeeeeeeeeee eeeeeeeeeeeeeeeeeeee ee eee eeeeeeeeeeeeeeeeeeee eeee 88.[888] Mee eeeee eeeeeeee ee eeeeeee eeee eeeeeee ee eeeeeeee ee Meeeee 88. Meeeeeeee ee eeee, eee eeeeeeeeeee ee eeeeeeee ee eeeeeeee, eeeeeeeee eee eee eeeeeeeee ee 8,8-eeeeeeeeeeeeeeeeeeeeeee eeeeeeeeeeeeeeeeeeee (88), eeeee eeeee ee eee eeeeeeeee-eeeeeeeeee eeeeeeee eeeeeeeeeeee.
Meeeee 88 Meeeeeeeeeeeeee Mee Meeeeeeee eeee eee Meeeeee ee eee Meeeeeeeeeeeee ee Meeeeeeeeeeeeeeeeeeeeeeeee eeee Meeeeeee Meeeeeeeeee[888]
Mee eeeeeeeee-eeeeeee eeeeeeeeeeeeeee eee 88 eee ee eeeeeeee eeee eee M′-[(8M-eeeeeee-8-ee)eeeeeeeee]-8-eeeeeeeeeeeeeeeeeeeeeee ee eeee eee eeeeeeeeeeeee eeeeeeeeee eeeeeeeeee ee eeeeeeeee eeee eeeeeeee(M) eeeeeeee (Meeeee 88).[888] Me eee eeeeee eeee, eee Meeee eeee eeee eeee ee ee eeeeeeeee eeeee.
Meeeee 88 Meeeeeeeeeeeeee Mee Meeeeeeee eeee eee Meeeeeeeeeeeee ee 8M-eeeeeeee-8-eeeeeeeeeeee ee 8-Meeeeeeeeeeeeeeee-8M-eeeeeeee[888]
Meeeeeeeeeee Meeeeeeee
8-Meeeee-8,8-eeeeeeeeeee-8-eee-8-eeeeeeeee Meeeeeeeeeeeeeeeeeee (Meeee 8, Meeee 8); Meeeeee Meeeeeeee:[888]
Mee eeeeeeeeeeeeee ee 8,8-eeeeeeee-8,8-eeeeeeeeeeeeeee (8.88 e, 88 eeee) eee eeeee ee e eeee ee MeMe8 (88.8 e, 88 eeee) ee MM8Me8/MMe8 (MMMMMMM: eeeee) (8:8; 888 eM) ee 8°M. Meeee eeeeeeee eee 88 e ee 8°M, eee eeeeeeeeeeee eeeeeeeee eeee eee eeeeeeeee ee eeeeeeeeee eeeee eee M8. Mee eeeee eeeeeee eeee eeeeeeee (8.88 e, 88% eeeee) eee eeeeeeeee ee 8,8-eeeeeeeeeeeeee ee 88°M. Meeeeeee ee eee eeee ee eee eeee eeeeee ee MMe8 eeeeeeee eeeeeeeeeeee eeee eeeeeee; eeeee: 8.88 e (88%); ee 88–88°M (eee).
8,8-Meeeeeeeeeeeee-8-eeeeeeeee Meeeeeeeeeeeeeeeeeee (88):[888]
MMMMMMM: Meeeeeee eeeeeeeeeee eeee ee e eeeeee eeeeeeee ee eee eeeeeee eee eeeeee eeeeeeeee eeee eeeee.
Mee eeeeeee eeeeeeeee eeee eeeeeeee ee MeMe8 (8.88 e, 88.8 eeee) ee e eeeeeeeeee ee M′-(8-eeeeee-8,8-eeeeeeee-8-eeeeeeeeeeee)-8-eeeeeeeeeeeeeeeeeeeeeee (88; 8.88 e, 8.8 eeee) ee MM8Me8 (88 eM) eee eeeeeee ee 88°M eee 88 eee. Meeeeeeeee, ee eee eeeeeeee, eee eee eeeeeeee eee eeeeeee eeee e eeee ee 88-eeeeeeeeeeeeeeeeeeeeeeee eeeeeeeeeeeeeeeeeeee (8.88 e, 88.8 eeee) ee MM8Me8 (88 eM). MMe8 (88 eM) (MMMMMMM: eeeee) eee eeeee, eee eee eeeeeee eee eeeeeee ee eeeee ee −88°M eee 8 e. Mee eeeee eeeeeee eee eeeeeeeee ee eeeeeeeeee eee eeeeeeee ee eeeeeeeeee ee ee 8,8-eeeeeeeeeeeeee. Meeeeeee ee eee eeee ee eee eeee eeeeee ee MMe8 eeeeeeee eeeeeeeeeeee eeee eeeeeee; eeeee: 8.88 e (88%); ee 888–888°M (eee).
References
[123] | Meee, M., Meee. Mee., (8888) 888, 888. |
[136] | Meee, M., Meeee. Meee., (8888) 88, 888; Meeee. Meee. Mee. Me. Meee., (8888) 8, 888. |