Navigation

0 Hits

  • Previous / Next

You are using Science Of Synthesis as a Guest.
Please login or sign up for a free trial to access the full content.
43.8.3.3.3 Method 3: Ruthenium-Catalyzed Reaction of an Alkyne with a 1,3-Diene

DOI: 10.1055/sos-SD-043-00462

Aitken, R. A.; Aitken, K.Science of Synthesis, (200843622.

Terminal alkynes react with dienes 143 and 145 when 12mol% of ruthenium catalyst is added to the reaction mixture to afford the products 144 and 146, respectively (Scheme 84).[‌259‌]

Meeeee 88 Meeeeeeeeeee ee Meeeee[‌888‌]

Meeeeeeeeeee Meeeeeeee

8-(Mee-8-eeee)eeeeeeeeeee [888, M8=(MM8)8Me]; Meeeeee Meeeeeeee:[‌888‌]

M eeeeeee ee [MeM8(MMe8)8] (88ee, 8.8eeee), eee-8-eee (8.8e, 88eeee), eeeeeeeee-8,8-eeeee (8.8e, 88eeee), eee eeeeeee (8eM) (MMMMMMM: eeeeeeeeee) eee eeeeee ee e eeeeee eeee ee 888°M eee 8e. Mee eeeeeee eee eeeeeeeee ee eeee eee eeeeeee; eeeee: 8.88e (88%); ee 888°M/8Meee.

References