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45.9.2.1.13 Method 13: Substitution via Organometallic Species

DOI: 10.1055/sos-SD-045-00322

Nishinaga, T.Science of Synthesis, (201045422.

2,5,7,10-Tetrakis(trimethylsilyl)bicyclo[4.4.1]undeca-1,3,5,7,9-pentaene (63) and its corresponding iodo analogue can be prepared by quenching organometallic species prepared from 37 [either by lithiation with a combination of butyllithium, potassium tert-butoxide, and tetramethylethylenediamine[‌85‌] or by mercuration with mercury(II) acetate][‌86‌] with the appropriate electrophile (Scheme 27).

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