You are using Science Of Synthesis as a Guest.
Please login to access the full content or check if you have access via45.13.1.1.2 Method 2: Cross-Coupling Reactions
Please login to access the full content or check if you have access via
DOI:
10.1055/sos-SD-045-00510
Black, D. A.; Fagnou, K., Science of Synthesis, (2010) 45, 549.
Compared to its use as a stoichiometric reagent, there are relatively few examples of copper being used as a catalyst for biaryl synthesis.[3,19] Recently, however, practical alternatives to palladium-catalyzed processes have been deployed. In these innovations the catalysts are often air- and moisture-stable, and frequently utilize inexpensive amine-based ligands, or even have no ligands at all. A variety of transmetalating agents may be employed, including boronic acids and organotin reagents.
References
| [3] | Meeeee, M.; Méeeeeee, M.; Meeee, M.; Meeeeee, M.; Meeeeee, M., Meee. Mee., (8888) 888, 8888. |
| [19] | Meeeeeeeee, M. M.; Meeeeeeee, M. M., Meeee. Meee. Mee., (8888) 888, 8888. |
Meeeeee Meeeeeeeeee
- 8.Meeeee-Meee, (8888) 88/8, 888.
- 8.Meeeee-Meee, (8888) 88/8e, 888.
Return to Top