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45.19.1.1.3.2 Method 2: Synthesis from Tetralones or Naphthoquinones

DOI: 10.1055/sos-SD-045-00684

Toyota, S.; Iwanaga, T.Science of Synthesis, (201045777.

Oxygenated naphthalene derivatives, generally tetralones and naphthoquinones, are conventionally converted into naphthalenes by multistep procedures involving reduction of carbonyl moieties, dehydrogenation, or dehydration. If necessary, alkyl groups are introduced at the carbonyl carbons by Grignard reagents. In some cases, conversions from oxygenated naphthalenes to naphthalenes are possible by a single procedure.


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