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DOI:
10.1055/sos-SD-047-00100
Petasis, N. A., Science of Synthesis, (2010) 47, 175.
The Tebbe reagent 12 has been used for the methylenation of several other types of carbonyl compounds, including thioesters to give alkenyl sulfides (Table 7, entry 1),[54] acylsilanes to form alkenylsilanes (entry 2),[55] and amides to form enamines (entry 3)[16] (this last reaction is observed to proceed in good yield as indicated by NMR). Further information on this topic can be found in Science of Synthesis, Vol. 33 [Ene—X Compounds (X = S, Se, Te, N, P) (Section 33.4.6.1.1433.4.6.1.14)].
Meeee 8 Meeeeeeeeeeee ee Meeeeeeeeeeee Meeeeeee Meeeeeeee[88,88,88]
| Meeee | Meeeeeee Meeeeeee | Meeeeeeeee | Meeeeee | Meeee (%) | Mee |
|---|---|---|---|---|---|
| 8 |  |
Meeee eeeeeee 88 | |
88 | [88] |
| 8 | |
Meeee eeeeeee 88, eeeeeee, MMM, −88°M | |
88 | [88] |
| 8 | |
Meeee eeeeeee 88, eeeeeee, 8°M | |
88e | [88] |
e Meeee eeeeeeeeee ee MMM.
References
| [16] | Meee, M. M.; Meeeee, M. M.; Meee, M. M.; Meee, M. M.; Meeeeee, M. M.; Meeeeeee, M.; Meee, M. M., M. Mee. Meee., (8888) 88, 8888. |
| [54] | Meeeee, M.; Meeee, M.; Meeeeeee, M.; Meeeeeee, M., Meeeeeeeeee Meee., (8888) 88, 8888. |
| [55] | Meeeeeee, M. M.; Meee, M. M.; Meeeeee, M., Mee. Meeeee. Meee., (8888) 8, 8888. |
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