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DOI: 10.1055/sos-SD-047-00322

Kostikov, R. R.; Khlebnikov, A. F.; Sokolov, V. V.Science of Synthesis, (201047812.

The thermal decomposition of alkyl halides under an inert atmosphere occurs at high temperatures to give alkenes. Thermolysis in the gas phase of 1- and 2-chlorododecanes at 400450°C provides mixtures of dodec-1-ene and dodec-2-ene. 1-Chloro-3,3-dimethylbutane at 545°C gives a mixture of 3,3-dimethylbut-1-ene and 2,3-dimethylbut-2-ene, resulting from rearrangement of an intermediate cationic species (see HoubenWeyl, Vol. 5/1b, pp 173179).

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