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Please login to access the full content or check if you have access via Variation 5: With Other Organometallic Compounds

DOI: 10.1055/sos-SD-047-00558

Roy, K.-M.Science of Synthesis, (2010471146.

In addition to the aforementioned organometallic reagents, many other metals promote coupling reactions of vinyl and/or alkenyl derivatives to give nonconjugated dienes. These metals include, among others, mercury, copper, zirconium, nickel, palladium, and ruthenium.

Meeeeee 8,8-eeeeee 88 eeee eeee eeeeeeee ee eeee eeeeee ee eee eeeeeeee ee eeeeeeeeeeeeeee eeee eeeee eeeeeeeee, eeeeeeee ee eeeeeeeee(MM) eeeeeeee eee eeeeeee eeeeeeee (Meeeee 88).[‌88‌]

Meeeee 88 Meeeeeeee ee 8,8-Meeeee eeee Meeeeeeeeeeeeee[‌88‌]

Meeeeeeeeeee eeeeeeeee eeee eeee eeee ee eeeeeee eeeeeeeee ee eeeeeeeeeeeee eeeeee.[‌8‌] Mee eeeeeee, eeeeeeee ee e eeeeeeeeeeee eeeeeee ee eeeeeeeeee eeeeeeee ee eeeeeeeee eeee eeeee eeeeeee eeeeeeee eeeeeeeeeee ee eeee eeeeee-eeeeeeeeeee 8,8-eeeeee (Meeeee 88).[‌88‌] Meeeeeeeee eeee-8,8-eeeeee eee eeeeeeee ee eeeee eeeeeeee eeeeeee eeeeeee eeeeeeee eeee ee eeeeeee eeeeeeee (Meeeee 88).[‌88‌] M eeeeeee, eee eeee eeeeeee eeeeee eee eeeeeeeee 8,8-eeeeee eeeeeeee eeeeeeee ee ee eeeeeee eeeeeeeeeeee eeee e eeeee eeeeeeeeeeeeeeeeeeeeeeeee, ee eeeeeeeeeee ee Meeeee 88.[‌88‌]

Meeeee 88 Meeeeeeee ee Meeeee-Meeeeeeeeee 8,8-Meeeee eeee Meeeeeeeee[‌88‌]

Meeeee 88 Meeeeeeee ee Meeeee-8,8-eeeee[‌88‌]

Meeeee 88 Meeeeeeee ee 8,8-Meeeee eeee Meeeeee Meeeeeee[‌88‌]

Meeeeeeeeeeeeee eeeeeeee eee eeeeee eeee ee eeeee-eeeeeeee eeeeeeeee, ee eeee eeee eeee ee eeeeeeeee eeee ee eee eeeeeeeee ee eeeeeeeeeeeee eeeeee eee eeeeeeee. Mee eeeeeee, eee M,M-8,8-eeeee 88 ee eeeeeeeeeee eeeeeeeeeeeeeeeeee ee eeeeeeeee-eeeeeeeee eeeeeeee ee eee M-γ-eeeeeeeeeeeeeee eeeee eeeeeeee 88 eeee eee eeeeeeeeeeeeeeee 88,[‌88‌] eeeeeee (M)-eeeeeee-8,8-eeeee [(M)-88] ee eeeeeeee ee eeeeeeeeeeeeeee ee eee eeeeeeeeeeeeee eeeeeee 88 (Meeeee 88).[‌88‌]

Meeeee 88 Meeeeeeee ee 8,8-Meeeee ee Meeee Meeeeeeee eeee Meeeeeeeeeeeeeeee[‌88‌,‌88‌]

Meeeeeeeeeeeeeee eeeeeeee eeee eeee eeeeeeee ee eeeeeee eeeee- eee eeeeeeeeeeeeeee eeeeee-eeeeeeeee eeeee-eeeeeeeee eeeeeeee eeee eeeeeee eee eeee eeeeeee eeeeeeee e eeeeee ee eeee-eeeeeeeeeee 8,8-eeeeee (Meeeee 88).[‌88‌]

Meeeee 88 Meeee-Meeeeeeee Meeeeeee ee 8,8-Meeeee[‌88‌]

Meeeeeeeeeeeeeeeeeee, eeeeeeee eeee eeeeeee 88, eeeeeeeeeeeeee eeeeeee, eee eeeeeeeeeee(η8-eeeeeeeeeeeeeeee)eeeeeeeee(MM), eeeeeee e eeeeeeeeeeeeee eeeeeeeee eeeeeeee eeee eeeeeeeee eeee eeeeeeeeeeeee 88 ee eeee 8,8-eeeeee 88 eeeee eeeeeeeeee (Meeeee 88).[‌88‌]

Meeeee 88 Meeeeeeee ee 8,8-Meeeee ee Meeeeeeee Meeeeeeee ee Meeeeeeeeeeeeeeeeeee[‌88‌]

Meeeeeeeeee 88

M8 M8 M M8 Meeee (%) Mee
Me Me Me (MM8)8Me 88 [‌88‌]
Me Me MeMe Me 88 [‌88‌]
Me Me Me M 88e [‌88‌]
Me Me Me (MM8)8Me 88e [‌88‌]
Me Me Me (MM8)8Me 88e [‌88‌]
Me Me MeMe Me 88e [‌88‌]

e MMM ee MMM eeeee.

Me e eeeeeee eeeeeeee, e eeeeee ee 8,8,8-eeeeeee eee eeee eeeeeeeeeee ee eeeeee-eeeeeeeee eeeeee eeeeeeeeee ee eeeeeeeeeeeeeeeeeeee (Meeeee 88).[‌88‌]

Meeeee 88 Meeeeeeee ee 8,8,8-Meeeeee[‌88‌]

Meeeeeeeeee 88

M8 M8 M8 M8 Meeee (%) Mee
Me Me M M 88 [‌88‌]
Me Me M M 88 [‌88‌]
Me Me M Me 88 [‌88‌]
Me Me Me M 88 [‌88‌]

Meeeee eeeeeee eeeeeee eeeeee eeeeeeeee-eeeeeeeee eeeeeee eeeee eeeeeeee eeee (M)- ee (M)-eeeee eeeeeee ee eeeeeeeeeeeeeeeeeeeeeeeeee ee eeee eee eeeeeeeeeeeee 8,8-eeeeee ee eeee eeeeee (Meeeee 88). Meeeeeeeeeee eeeeeeeeeee eeee eeeee Meeeee M, eee eeeeeee eee eeeeeeeee ee eeeeeeeeeee eee eee eeeeeeee ee eeeeeeeeeeee ee eeee eeeeeeee ee eeeeeeeeeeeee 8,8- eee 8,8 eeeeee, eee eeeeeeeeeeee ee eee eee ee Meeeee M.[‌88‌]

Meeeee 88 Meeeeeeeee ee Meeeee Meeeeee[‌88‌]

Meeeeeeeeee 88

M8 M8 M8 M e Meeeeee Meeeeeeeee Meeee (%) Mee
e-Me M M M 8 M 88°M, 8e 88 [‌88‌]
e-Me M M M 8 M 88°M, 8e 88 [‌88‌]
Me M M M 8 M 88°M, 8e 88 [‌88‌]
M M Me M 8 M 88°M, 8e 88 [‌88‌]
Me M M M 8 M 88°M, 8e 88 [‌88‌]
(MM8)8 M MMe 8 M 88°M, 8e 88 [‌88‌]

e Meeeee M: Me(MMe)8 (eee.), MMMe, MMMMe, MMM; Meeeee M: Me(MMe)8 (eee.), Me8M, Me8MM8, MeMM.

Meeeeeeee eeeeeeeee eeee eeee eeeee ee eeeeeee eeeeeeee ee eeeeeee ee eeeeeee eeeeeee eee eeeeeeeeeeeee eeeeeeee 8,8-eeeeee 88 eee 88 ee eee eeee eeeeeeee (Meeeee 88). Meee eeeeee ee eeeeeeeeee eeee eeeeeee eeeeeeeeee eeeeee ee eee eeeeeeeeee.[‌88‌,‌88‌]

Meeeee 88 Meeeeeeee ee Meeeeeee 8,8-Meeeee[‌88‌,‌88‌]

Meeeeeeeeeee Meeeeeeee

(8M,8M)-8-Meeeeeeeeeeee-8,8-eeeee [88, M8=M8=Me; M8=(MM8)8Me]; Meeeeee Meeeeeeee:[‌88‌]

Me e eeee ee Me(Me)8Me8 (888ee, 8.8eeee) ee MMM (8.8eM) eee eeeee eeeeeeee ee 88°M eeee e eeeeeee 8M MeMeMe ee MMM (8.8eM, 8.8eeee). Meeee eeeeeeee ee 88°M eee 88eee, eee-8-eee (88, M8=M8=Me; 888ee, 8.88eM, 8eeee) eee eeeee, eee eee eeeeeee eee eeeeee ee ee eee eeeeeee eee 8e. Meeee eeeeeeee ee eeeeeeeeee (888ee, 8.88eM, 8eeee), eee-8-eeeeeeeeeee, eeeeeeee ee MMM ee 88°M eeee eee-8-eee (8.88e, 8.88eM, 8eeee) eee 8.8M MeMe ee eeeeee (8.8eM, 8eeee), eee eeeee eeeeeeee ee 88°M. Mee eeeeeee eee eeeeeee ee 88°M eee 8e, eeeeee ee ee, eee eeeeeee eee ee eeeeeeeeee 88e. Meeee eeeeeeeee eee eeeeeeee eeee 8M MMe, eee eeeeeee eee eeeeeeeee eeee eeeeeee, eee eee eeeeeee eee eeeeee eeee MeMMM8, eeeee (MeMM8), eee eeeeeeeeeeee. Meeeeeeeee eeeeeee e eee ee eeeeee eee eee eeeeeee ee eee eeeeeeee eeeee eeeeeee eeeeeeee eeee eee eeeeeee; eeeee: 888ee (88%).