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DOI: 10.1055/sos-SD-048-00026

Wicha, J.Science of Synthesis, (200948111.

Hydrogen selenide, formed in situ from elemental selenium, carbon monoxide, and water, acts in the presence of a base (1,5-diazabicyclo[5.4.0]undec-5-ene) as an effective reducing agent for transforming alkyl aryl ketones into the parent hydrocarbons.[‌96‌] The reactions are carried out in a stainless steel autoclave under a carbon monoxide atmosphere (29.6atm) at 120°C. Representative results are shown in Scheme 23.

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