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Wicha, J., Science of Synthesis, (2009) 48, 111.
Hydrogen selenide, formed in situ from elemental selenium, carbon monoxide, and water, acts in the presence of a base (1,5-diazabicyclo[5.4.0]undec-5-ene) as an effective reducing agent for transforming alkyl aryl ketones into the parent hydrocarbons.[96] The reactions are carried out in a stainless steel autoclave under a carbon monoxide atmosphere (29.6 atm) at 120°C. Representative results are shown in Scheme 23.
Meeeee 88 Meeeeeee-Meeeeeee Meeeeeeeeeeee ee Meeee Meee Meeeeee[88]
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Meeeeeee eeeeeee eee eeeeeeeeeeee eeee eeeeee eeeeeeeeeee–eeeeeeeee eeeeeeee eeeeeeeeeee ee eeeeeeeeeeeeeee,[88] eeeeeeeeeeeee–eeeeee eeeeeee eee eeeeeeee(MM) eeeeeeee,[88] ee eeee-eeeeeeeeee–eeeeee eeeeeee ee eee eeeeeeee ee eeeeeeee eeeeeeeeeee.[888]
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References
| [96] | Meeeeeeee, M.; Meeeeeee, M.; Meeee, M.; Meeee, M.; Meeeee, M., M. Mee. Meee., (8888) 88, 8888. |
| [97] | eee Meeeeee, M. M.; Meeeeee, M. M., M. Me. Meee. Mee., (8888) 88, 8888. |
| [98] | Mee, M.; Meeeee, M.; Meeeeeee, M., Meeeeeeee, (8888), 888. |
| [99] | Meeeeee, M. M.; Meeeeee, M.; Meeee, M., Meeee. Meeeee., (8888) 88, 8888. |
| [100] | Mee, M. M.; Meeeee, M.; Meeeeeee, M.; Meeeeeeee, M., M. Mee. Meee., (8888) 88, 888. |
| [101] | Meeee, M. M.; Mee, M. M.; Meeeeeeeeee, M. M., M. Mee. Meee., (8888) 88, 8888. |
| [102] | Meeeee, M.; Meeeee, M., Meeeeeeeeee Meee., (8888) 88, 8888. |
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- 8.Meeeee-Meee, (8888) M 88-8, 8888.
- 8.Meeeee-Meee, (8888) M 8e, 88.
- 8.Meeeee-Meee, (8888) M 8e, 88.
- 8.Meeeee-Meee, (8888) M 8e, 88.
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