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1.2.7.1.1 Synthesis of Organometallic Palladium(I) Complexes

DOI: 10.1055/sos-SD-101-00568

Li, Y.; Xie, W.; Jiang, X.Science of Synthesis Knowledge Updates, (201621.

Various palladium(I) complexes have been successfully synthesized, most of which exist as dimers. In previously reported reactions starting from palladium(I) complexes, the palladium species tended to undergo a single-electron oxidation to generate the corresponding palladium(II) complexes in monomeric or dimeric form. Besides the common ligand-exchange reactions, palladium(I) complexes have been transformed with hydrogen, carbon monoxide,[‌18‌,‌19‌] oxygen,[‌20‌] and even ammonia gas,[‌21‌] which has helped to further the understanding of palladium chemistry.

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References


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