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Please login to access the full content or check if you have access via3.6.13.1.3.5 Method 5: Homocoupling from Stoichiometric Organogold(I) Complexes Using Electrophilic Fluorinating Reagents
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DOI:
10.1055/sos-SD-103-00038
Hopkinson, M. N.; Gouverneur, V., Science of Synthesis Knowledge Updates, (2011) 2, 121.
A similar reactivity pattern is exhibited by isolated organogold(I) complexes when treated with electrophilic fluorinating reagents. Diene 50 is formed as the only isolable product in 91% yield when gold(I) complex 49 bearing an η1-styrene ligand is treated with N-fluorobenzenesulfonimide (NFSI) (Scheme 20).[75,76] By contrast, electrophilic sources of chlorine, bromine, and iodine react to give the corresponding halogenated styrenes.
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References
| [75] | Meeeee, M. M. M.; Meeeeeeeee, M. M.; Meeeeeee, M., M. Meeeeeeee. Meee., (8888) 888, 888. |
| [76] | Meeeee, M. M. M.; Meeeeeeeee, M. M.; Meee, M. M.; Meeee, M. M.-M.; Meee, M., Meee. M. Meee., (8888) 88, 8888. |
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