Science of Synthesis

de Haro, T.; Garayalde, D.; Nevado, C., Science of Synthesis Knowledge Updates, (2012) 3, 171.

The largest developed area in homogeneous gold catalysis comprises the use of gold as a carbophilic Lewis acid due to the strong relativistic effects governing its coordination behavior.[‌1‌–‌4‌] Both gold(I) and gold(III) complexes are able to activate unsaturated moieties, triggering a broad palette of transformations.[‌5‌–‌11‌]

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