Science of Synthesis

Mathey, F., Science of Synthesis Knowledge Updates, (2012) 4, 358.

The reaction of metal halides with phospholide ions is the standard route to η5-phospholyl complexes; it has been used with the metals listed in Section ‌9.14.4.3‌. The availability of difunctionalized phospholides has led to a series of studies focused on the synthesis of di- and tetrafunctionalized phosphametallocenes such as ‌25‌ (‌Scheme 34‌).[‌88‌–‌90‌]

‌Meeeee 88‌ Meeeeeeee ee e Meeeeeeeeee Meeeeeeeeeeeeeeeee[‌88‌]

Mee eeeeeee ee eee eeeeeeee ee eeeeeeeeeeeeee eeeeeeeeeeee eeee eeeeeeeeee eeeee eeee­eeeee eeeeeeeeeeeee eeeeeee ee eeeee eeeeee, ee eeeee ee Meeeeeeeee.[‌88‌]

Meeeeeeeeeee Meeeeeeee

8,8′,8,8′-Meeeeeeeeee-8,8′,8,8′-eeeeeeeeeeeee-8,8′-eeeeeeeeeeeeeeeeee (‌88‌):[‌88‌]

8,8-Meeeeeee-8-eeeeeeeeeeeeeee (8 e, 8.88 eeee) ee eee MMM (88 eM) eee eeeeeee ee eeeee eeee ee eeeeee ee Me eeee eee 8 e ee ee. Meeee eeeeee Me eee eeeeeee, eee eeee eee eeeeeee eeee e-MeMe (8.8 eM, 8.88 eeee) eee eeeeee ee 88 °M eee 8 e. Meeeeeee eeeeeeee (8.8 eM, 8.88 eeee) eee eeeee eeeeeeee ee −88 °M. Mee eeee eee eeeeee ee ee eee eeeeeee ee eeee eee 88 eee. e-MeMM (8.888 e, 8.88 eeee) eee eeeee ee 8 °M. Mee eeeeeeeee eeeeeee eee eeeeee ee 88 °M eee 8 e. M eeeeee eeeeeeeeee ee eeeeeeee eeeeeeee (8.8 eM, 8.88 eeee) eee eeeee ee −88 °M, eeeeeeeeeee eeeeeeee ee eeeeeeee ee e eeeeee eeeeeeeeee ee e-MeMM (8.888 e, 8.88 eeee) ee 8 °M. Mee eeeeeeeee eeeeeee eee eeeeeee ee 88 °M eee 8.8 e. Mee eeee eee eeeeee ee 8 °M, MeMe8 (8.888 e, 88.88 eeee) eee eeeee, eee eee eeeeeee eee eeeeeee ee ee eee 88 eee. Meee, MeMe8 (8.888 e, 8.88 eeee) eee eeeee ee ee. Mee eeee eee eeeeeee eee 88 e ee ee. Mee eeeee eeeeeee eee eeeeeeee eeeeeee eeeeee eee eee eeeeeeeeeeee. Meeeeeeeeeee eee eeeeeeeee eee eeeeee eeeeeeeeeeeeee (eeeeee eee, MM8Me8/eeeeeee 8:8). Mee eee eeee eee eeeeeeeee eee eeeeeeeeeeee; eeeee: 8.888 e (88%); 88M MMM (MM8Me8, δ): −88.8.

References