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9.14.4.3.3.1 Variation 1: Via Intermediate 1-Stannylphospholes

DOI: 10.1055/sos-SD-109-00281

Mathey, F.Science of Synthesis Knowledge Updates, (20124359.

Whenever a redox reaction can occur at the transition metal center (reduction of high-valent metals), the use of alkali metal phospholides might become troublesome. In such a case, their replacement by 1-stannylphospholes can provide a satisfactory solution. Such a technique has been used for the synthesis of phosphametallocenium cations of rhodi­um(III) and iridium(III).[‌91‌]

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