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DOI: 10.1055/sos-SD-109-00525

Tobrman, T.Science of Synthesis Knowledge Updates, (20241147.

As mentioned previously, phospholes are frequently oxidized to phosphole oxides because of the increased stability of pentavalent 1H-phospholes. The opposite approach, the reduction of phosphole oxides to trivalent phospholes, is rather rare. A representative example is the selective conversion of phosphole oxide dimer 51 into the corresponding phosphine–borane complex 52 (Scheme 22).[‌79‌]

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