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9.14.5.3.1 Synthesis from Phospholide Ions

DOI: 10.1055/sos-SD-109-00525

Tobrman, T.Science of Synthesis Knowledge Updates, (20241154.

Probably the most popular approach for the preparation of η5-phospholyl complexes is the reaction of phospholide ions with transition-metal salts. This approach benefits from the high aromaticity of phospholide ions and their availability. A cobaltocenium complex 77 was synthesized by this approach in 86% isolated yield from potassium phospholide 76 (Scheme 31).[‌136‌]

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