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10.23.4.1.1.5.1.7 From an N-(2-Diazophenyl)-N-methylpyridin-3-amine

DOI: 10.1055/sos-SD-110-01096

Joule, J. A.Science of Synthesis Knowledge Updates, (20182336.

The Pschorr reaction of N-(2-aminophenyl)-N-methylpyridin-3-amine (396) produces a mixture of the two possible products of radical cyclization onto the pyridine ring: the 5-methyl-5H-pyrido[3,2-b]indole (398) and the 9-methyl-9H-pyrido[3,4-b]indole (397; Scheme 382).[‌173‌] For an experimental procedure see Section 10.23.2.1.1.5.1.6.

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