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Please login to access the full content or check if you have access via22.4.9.2.1.2 Silylation of N,N,N′-Trimethylformimidamide
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Huang, H.; Deng, G.-J.; Ji, X., Science of Synthesis Knowledge Updates, (2024) 2, 452.
The N-silylated trimethylformimidamide trifluoromethanesulfonate 3 can be obtained in almost quantitative yield by treatment of N,N,N′-trimethylformimidamide with trimethylsilyl trifluoromethanesulfonate (Scheme 2).[4] Further treatment of 3 with the weakly nucleophilic bulky base lithium hexamethyldisilazanide leads to formation of a silylformamidine, which can be considered as a latent nucleophilic carbene.[4,5]
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References
| [4] | Meeeeeeee, M.; Meeeee, M.; Meeeeee, M.; Meeeeeeee, M.; Meeeeeee, M. M.; Meeeeee, M. M.; Meeeeeeee, M. M.; Meeeeee, M., M. Mee. Meee., (8888) 88, 888. |
| [5] | Meeeeeeee, M.; Meeeee, M.; Meeeeee, M.; Meeeeeee, M.; Meeeeee, M., Mee. M. Meeee. Meee., (8888), 8888. |
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