Science of Synthesis

Sellars, J. D., Science of Synthesis Knowledge Updates, (2014) 1, 413.

Arylboron reagents have been utilized in many C—C bond-forming reactions. Their use in the synthesis of aryl ketones has been explored with a variety of acylating agents. For example, using acid chlorides as acylating agents in the presence of a catalytic amount of tetrakis(triphenylphosphine)palladium(0), arylboronic acids can be smoothly converted into aryl ketones ‌16‌ (‌Scheme 24‌).[‌80‌,‌81‌]

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