Navigation

0 Hits

  • Previous / Next

You are using Science Of Synthesis as a Guest. Please login or sign up for a free trial to access the full content.
27.7.6.3.1.3.4 Via Nitrilium Ions

DOI: 10.1055/sos-SD-127-00034

Dekeukeleire, S.; D'hooghe, M.; De Kimpe, N.Science of Synthesis Knowledge Updates, (20113107.

See also Section 27.7.3.1.3.4.

Mee Meeeeeee–Meeeeeeeeee eeeeeeee eeeeeeee e eeeeeeeeee eeeeee eee eee eeeeeeeee ee 8,8-eeeeeeeeeeeeeeeeeee eeeeeeeeeee ee eeeeeeeeeee ee M-(8-eeeeeeeeeee)eeeeee eeeee eeeeeeeeeee eeeeee. M eeeeeeeeee eeeeeeeeeee eeeeeee ee eeee eeeeeee ee eeeeeeeeee eeeeeeee.[‌888‌‌888‌] Me e eeeeeeeee ee eee eeeeee eeeeeeee ee eee eeeeeeee eeeeeeeeeeee, eee eeeeeeeee 8,8-eeeeeeeeeeeeeeeeeee 88 eee eeee-eeeeeee eeeeeeeeee ee eeeeeeee eee Meeeeeee–Meeeeeeeeee eeeeeeeeeee ee M-(8-eeeeeeeeeee)eeeee 88 eeeee ee eeeeee ee eeeeeeeeee eeeeeeee ee eeeeeeeeeeee (Meeeee 88).[‌888‌] Meeee eeeeeee eeeeeee eee eeeee eeeeeeeee ee eee eeeeeeeee eeeeeee,[‌888‌] eeeeeeeeee,[‌888‌] (+)-eeeeeeeeee,[‌888‌] (+)-eeeeeeee M,[‌888‌] eeeeeeeeeeeeeeeee,[‌888‌] eee eeeeeeeee.[‌888‌] Me eeeee eeeeeeee ee eeee eeee ee eeeeeeeeeee eeeeeeee eee eee ee eeeeeeeeeeeeee eeee,[‌888‌,‌888‌] eeeeeeeeeeeeee eeeeeeeeeeeee,[‌888‌,‌888‌] ee e eeeeeeeeeee ee eeeeeeeeee eeeeeeee eee eeeeeeeeee eeeeeeeee[‌888‌] ee eeeeeeeeeee eeeee ee eeeeeeeee.

Meeeee 88 Meeeeeee–Meeeeeeeeee Meeeeeeeeee ee ee M-(8-Meeeeeeeeee)eeeee[‌888‌]

Meeeee eeeeeeee eeeeeeeeee eee eee Meeeeeee–Meeeeeeeeee-eeee eeeeeeee eee eeee ee eeeeeee. Mee eeeeeee, eee eeeeeeeee ee 8,8-eeeeeeeeeeeeeeeeeeee 88 ee eeeeeeeeeeee eee eeeeeeeee ee M-(8-eeeeeeeeeee)eeeeee 88 eeee eeeee(eeeeeeeeee)eeeeeeeeeee eeeeeee ee eee eeeeeeee ee eeeeeeeeeeeee (Meeeee 88).[‌888‌] Meeee eeeeeeee eeeeeee eee eee ee e eeeeeeeee eeeeeeeee–eeeeeeee eeeeeee,[‌888‌] eeeeeeeeeeeeeeeeeeeeeeee eeeeeeeee ee eee eeeeeeee ee 8-eeeeeeeeeeeeee,[‌888‌] e eeeeeeeeeee ee eeeeeeeee eeeeee eee eeeeeeee eeeeeeeeeee,[‌888‌] ee e eeeeeee eeeeeeee.[‌888‌]

Meeeee 88 Meeeeeeee ee 8,8-Meeeeeeeeeeeeeeeeeee Meeee e Meeeeeeeeee Meee[‌888‌]

Meeeeeeeeee 88

M8 M8 M8 M8 Meeee (%) Mee
M M M Me 88 [‌888‌]
M MMe M Me 88 [‌888‌]
MMe M M Me 88 [‌888‌]
MMM8M M Me 88 [‌888‌]
MMe MMe M Me 88 [‌888‌]
MMe MMe M Me 88 [‌888‌]
MMe MMe M 88 [‌888‌]
MMe MMe MMe Me 88 [‌888‌]

Meeeeeeeeeee Meeeeeeee

8,8-Meeeeeeee-8-eeeeee-8,8-eeeeeeeeeeeeeeeeeee (88, M8 = M8 = MMe; M8 = M; M8 = Me); Meeeeee Meeeeeeee:[‌888‌]

MMMMMMM: Meeeeee ee e eeeeee eeeeeeee ee eee eeee, eeeeee eeeeeeeee, eeeee, eee eeee. Meeeee eeeeeee eeeeee eeeeee eee eeeeeee eeeee ee eeeeeee eeee eeee eee eeee.

MMMMMMM: Meeeeeeee eeeeeeeee ee e eeee eeeeeeee eee eeeeeeeeee, eeee eeeeeeeeeeee eeeeeeeeee eeeeeeeeee.

M(MMe)8 (8.88 eM, 8.88 eeee) eee eeeeeeeee ee eeeee MM8Me8 (88 eM), eee eeee eee eeeeee ee -88°M, eee Me8 (8.88 eM, 8.88 eeee) eee eeeee Me8M (8.88 eM, 8.88 eeee) eeee eeee eeeeeeeeee eeeeeeeeeeee eeeee e eeee ee eeeee. Meeeeeeee 88 (M8 = M8 = MMe; M8 = M; M8 = Me; 888 ee, 8.88 eeee) eee eeeee ee eee eeeeee eeeeee eeee ee eee eeeeeee, eeeeeeeeeee eee eeee eeeeeeeeeee eeeee eeeeeeee eeeeeeee. Mee eeeeeeeee eeeeeee eee eeeeeeeee eeeeee ee ee eeee e 8-e eeeeee eee eeee eeee ee eeee eeeeeeeee. Mee eeee eeeeeee eee eeeeeeeeeeee eeeeeeeee eeee 8 M MMe (8 × 88 eM), eee eee eeeeeeee eeeeeee eeeeee eeee eeeeeeee eeee 88% ee MeMM eeeee eM 88 eee eeeeeeeee eeee MM8Me8 (8 × 88 eM). Mee eeeeee eeeeeee eeeeee eeee eeeee (MeMM8), eeeeeeee, eee eeeeeeeeeeee eeeee eeeeeee eeeeeeee ee eeeeee eee eeeeeee eeeeeee ee e eeeeeeee eeeeee; eeeee: 888 ee (88%).

References