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DOI:
10.1055/sos-SD-138-00067
Vil’, V. A.; Bityukov, O. V.; Terent’ev, A. O., Science of Synthesis Knowledge Updates, (2019) 3, 392.
Great progress has been made in the selective synthesis of geminal bishydroperoxides directly from ketones or aldehydes and hydrogen peroxide, overcoming the problems with this route mentioned in Section 38.11.2. A wide range of Brønsted and Lewis acids have been used as catalysts, and methods using heterogeneous supported catalysts have also been developed.
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