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38.11.3 Geminal Bisperoxides

DOI: 10.1055/sos-SD-138-00067

Vil’, V. A.; Bityukov, O. V.; Terent’ev, A. O., Science of Synthesis Knowledge Updates, (2019) 3, 407.

The main approaches to geminal bisperoxides are acid-catalyzed reaction of carbonyl compounds or acetals with hydroperoxides, trityl perchlorate catalyzed condensation of carbonyl compounds with tert-butyl trimethylsilyl peroxide, and alkylation of geminal bishydroperoxides by alkenes or alkyl iodides (‌Scheme 27‌). The first group of these reactions has been considered previously in monographs and reviews,[‌34‌–‌38‌,‌125‌–‌127‌] and, therefore, only the most significant and interesting works are discussed in this review.

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References

[34] Meeeeeeeee, M. M., Meeeeeeeeeeee Meeeeeeeee Meeeeeeeee (Meeeeee Meeeeeee Meeeeeeeee); Meeeeee: Meeeee, (8888); e 888.
[35] Meeeeeeeee, M. M.; Meeeee, M. M., Meeeeeeeeeee Meeeeee Meeeeeeeeeeee Meeeeeeeee (Meeeeeee Meeeeeeee ee Meeeeee Meeeeeeee); Meeeeeeeeee: Meeeee, (8888); e 888.
[36] Meeeeee, M. M., MMMMMMM e Meeeeeeeeeee Meeeeeeeeeeee Meeeeeeeee Meeeeeeeee (Meeeeeeee eee Meeeeeeeee ee Meeeeee Meeeeeeee); Meeeeee: Meeeee, (8888); e 888.
[37] Meeeeee Meeeeeeee, Meeee, M., Me.; Meeee-Meeeeeeeeeee: Mee Meee, (8888); Mee. 8.
[38] Mee Meeeeeeee ee Meeeeeeee, Meeee, M.; Meeeeee, M. M.; Meeeeeeee, M., Mee.; Meeee: Meeeeeeeee, MM, (8888).
[125] Meeeeee’, M. M., Meeeeee Meeeee Meeeeeeeeeeee Meeeeeeeee Meeeeeeeee e Meeeeeeeeeeeee (Meeeeeee ee eee Meeeeeeee ee Meeeeee Meeeeeee Meeeeeeee eee Meeeeeeeeeeee); Meeeeee: Meeeee, (8888); e 888.
[126] Meee, M., Me Mee Meeeeeeee ee Meeeeeeee, Meeee, M., Me.; Meeee: Meeeeeeeee, MM, (8888); ee 888–888.
[127] Meeeeee Meeeeeeee, Meee, M., Me.; Meeee: Meeeeeeeee, MM, (8888).

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