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38.11.3 Geminal Bisperoxides

DOI: 10.1055/sos-SD-138-00067

Vil, V. A.; Bityukov, O. V.; Terentev, A. O.Science of Synthesis Knowledge Updates, (20193407.

The main approaches to geminal bisperoxides are acid-catalyzed reaction of carbonyl compounds or acetals with hydroperoxides, trityl perchlorate catalyzed condensation of carbonyl compounds with tert-butyl trimethylsilyl peroxide, and alkylation of geminal bishydroperoxides by alkenes or alkyl iodides (Scheme 27). The first group of these reactions has been considered previously in monographs and reviews,[‌34‌‌38‌,‌125‌‌127‌] and, therefore, only the most significant and interesting works are discussed in this review.

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