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DOI:
10.1055/sos-SD-138-00067
Vil’, V. A.; Bityukov, O. V.; Terent’ev, A. O., Science of Synthesis Knowledge Updates, (2019) 3, 419.
Bis(1-hydroperoxyalkyl) peroxides [1,1′-bis(hydroperoxy)bis(alkyl)peroxides] can be synthesized from carbonyl compounds, acetals, or bishydroperoxides using hydrogen peroxide and various acids (Scheme 40). Substitution of a hydroxy group for a hydroperoxy group in 1-hydroperoxyalkyl 1-hydroxyalkyl peroxides also leads also to bis(1-hydroperoxyalkyl) peroxides (Scheme 40). Other miscellaneous approaches to bis(1-hydroperoxyalkyl) peroxides involve ozonolysis of enol ethers or alkenes and treatment of ethers with oxygen (not presented in Scheme 40).
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