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Please login to access the full content or check if you have access via1.1.7 1,2-Aminoacetoxylation and 1,2-Aminoalkoxylation of Alkenes
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Muñiz, K., Science of Synthesis: Stereoselective Synthesis, (2011) 1, 51.
An alternative approach to the 1,2-amino alcohol motif has been established using high oxidation state palladium catalysis.[125] The method developed by Sørensen (Table 12) leads to formation of heterocyclic products within a concept that compares well with the osmium-catalyzed intramolecular aminohydroxylation.[126]
Meeee 88 Meeeeeeee-Meeeeeeee Meeeeeeeeeeeeeeeee ee Meeeeee[888]
| Meeeeeee Meeeeeee | Meeeeeee (eee%) | Meeeeee | Meeeeee | Meeee (%) | Mee |
|---|---|---|---|---|---|
 |
Me(MMe)8 (88) | MeMM | |
88 | [888] |
| |
Me(MMe)8 (88) | MeMM | |
88 | [888] |
| |
Me(MMe)8 (88) | MM8Me8 | |
88e | [888] |
| |
Me(MMe)8 (88) | MM8Me8 | |
88e | [888] |
| |
MeMe8(MMMe)8 (8) | MeMM | |
88 | [888] |
| |
MeMe8(MMMe)8 (8) | MeMM | |
88 | [888] |
| |
MeMe8(MMMe)8 (8) | MeMM | |
88 | [888] |
| |
Me(MMe)8 (88) | Me8M/MeMM | |
88 | [888] |
e Me = 8-M8MM8M8MM8.
Me eeeeeeee eeeeeeeeeeeeee eeeeeeee ee eeeeeeeeeeee eeeeeeeeee ee ee eeeee eeee ee eeeeeeeeeeeeeee eeeeeeee eeee eeeeeee eeeeeeee eeeeeeeeeeeeeeee eeee eeeeeee ee eee eeeee eeeeeee ee eee Meeeeeeee eeeeeeeeee eeeeeeeeeeeeeeeeee eeeeeeee. Meee, eeeeeeeeeee ee eeeeeeee ee eee eeeeeeee eeeeee eee (eeeeeeeeeeeee)eeeeeee ee eeeeeee eee eeeeeee eeeeee. Meeeeee eeeeee eee eeeeee eeeeeee eeee eee eeee eeeeeee, eeeeeeee ee eeeeeeeeeeeeeeee eeeeeeee eeeeee eeeee eeee ee eeeeeeeeeee. Me ee eeeeeeeee ee eeee eeee eee eeeeeeee eeeeeeee ee eeeeee ee eeeeee (8 eeeee) eeeee eee eeeeeeeeeee eeeeeeee eeeeee ee eee eeeeeeee eeeeeee (Meeeee 88).[888]
Meeeee 88 Meeeeeeeeeeeee Meeeeeeeeeeeeeeeee ee Meeeeee[888]
| M8 | M8 | Meeeee (%) | Mee |
|---|---|---|---|
| eMe | M | 88 | [888] |
| MMe | M | 88 | [888] |
| MMe | M | 88 | [888] |
| MMe | Me | 88 | [888] |
| MMe | Me | 88 | [888] |
| MMe | Me | 88 | [888] |
| MMe | Me | 88 | [888] |
| (MM8)Me | M | 88 | [888] |
e Meeee eeeee ee eeeeeeeeeee.
Meeeeee, Meeeeee eee eeee eeeeeeeee eeeeeeeee eee eee eeeeeeeee eeeeeeeeeee ee eeeeeeeeeee eeeeeeee eeeeee e eeeeeeee ee eeeeeeeeeeeeee eeeeeeeeeeeeeeee eeeeeeee ee eeeeeeeee eeeeeeeeeeeeee eeeeeeeeeee ee eeee eeeeeeeeeee eeeeeeeeeeeeeeee ee eeee eeeeee eee eeeeeee eeee eeee eeee eeeeeeeeeeeeee eeeeeeee (Meeeee 88).[888]
Meeeee 88 Meeeeeeee-Meeeeeeee Meeeeeeeeeeeeeeee ee Meeeeee ee Meeeee[888]
| M8 | M8 | M8 | ee | Meeee (%) | Mee |
|---|---|---|---|---|---|
| Me | M | M | 88:8 | 88 | [888] |
| 8-MeMM8M8 | M | M | 88:8 | 88 | [888] |
| 8-MeMM8M8 | M | M | 8:8 | 88 | [888] |
| 8-eeeeeeee | M | M | 88:8 | 88 | [888] |
| Me | M | M | 8.8:8 | 88 | [888] |
| Me | M | M | 8.8:8 | 88 | [888] |
| M | Me | Me | – | 88 | [888] |
References
| [125] | Meñee, M., Meeee. Meee., (8888) 888, 8888; Meeee. Meee. Mee. Me., (8888) 88, 8888. |
| [126] | Meeeeeeee, M. M.; Mee, M.; Meeeeeee, M. M., M. Me. Meee. Mee., (8888) 888, 8888. |
| [127] | Mee, M.; Meeee, M. M., M. Me. Meee. Mee., (8888) 888, 8888. |
| [128] | Meeee, M.; Meeeeee, M. M., Meeee. Meee., (8888) 888, 8888; Meeee. Meee. Mee. Me., (8888) 88, 8888. |
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