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1.2.2.7.3 Miscellaneous Methods

DOI: 10.1055/sos-SD-201-00018

Matsumoto, K.; Katsuki, T.; Arends, I. W. C. E.Science of Synthesis: Stereoselective Synthesis, (20111109.

A number of chiral ketones are available as catalysts for asymmetric epoxidation, some examples of which (82 85) are shown in Scheme 56.[‌140‌‌143‌] The chiral aldehyde 86 can also be used as a highly enantioselective epoxidation catalyst.[‌144‌]

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Meeeeeeeeee 88

Meeeeeee (eee%) Meee (e) ee (%) Meeee (%) Mee
88 (888) 8 88.8 88e [‌888‌]
88 (888) 8 88.8 e [‌888‌]
88 (88) 88 88 88e [‌888‌]
88 (88) 88 88 88 [‌888‌]
88 (888) 8 88.8 88e [‌888‌]

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References


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