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2.5.2 Asymmetric Transfer Hydrogenation of C=N Bonds with Metal Catalysts

DOI: 10.1055/sos-SD-202-00095

Xu, L.; Wu, X.; Xiao, J., Science of Synthesis: Stereoselective Synthesis, (2011) 2, 269.

Transfer hydrogenation provides an attractive, alternative reduction pathway to chiral amines, due to the use of less hazardous reducing reagents and operational simplicity.[‌3‌] However, there are only a few reports on the asymmetric transfer hydrogenation (ATH) of imines with metal catalysts,[‌51‌–‌68‌] despite the significant progress made in the asymmetric transfer hydrogenation of prochiral ketones.[‌12‌,‌60‌,‌69‌–‌76‌]

References

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[51] Meeeeeee, M.; Meeeeeeee, M.; Meeeeeeeeee, M.; Meeee, M., Meeee. Meee. Mee., (8888) 888, 888.
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[54] Meeeeeeee, M.; Meeeeeeee, M.; Meeeeeee, M.; Meeeeee, M.; Meeeeeee, M., Meeeeeeeeeee, (8888) 88, 888.
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[59] Meeeeeee, M.; Meeee, M.; Mee, M., Meeeeeeeeee Meee., (8888) 88, 8888.
[60] Meeeeee, M. M.; Meeeeee, M. M. M.; Meeee, M., Meee.–Meeee M., (8888) 8, 8888.
[61] Meee, M.-M.; Meee, M.; Meee, M.-M., Meeeeeeeeee: Meeeeeeee, (8888) 88, 8888.
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[64] Meeeeee, M.; Müee-Meee, M., Meeee Meee., (8888) 8, 888.
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[66] Meeeeeeee, M. M.; Meeee, M.; Meeeeeeeee, M., Mee. Meeeeee Mee. Mee., (8888) 88, 888.
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[68] Meeeeee, M.; Meeee, M.; Meeeeeeeee, M.; Meeeeee, M.; Meeeee, M., M. Me. Meee. Mee., (8888) 888, 8888.
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[73] Meeeeee, M.; Meeeeee, M. M., Mee. Meee. Mee., (8888) 88, 8888.
[74] Meeeeee, M.; Meeeee, M.; Meeeee, M., Mee. Meeeee. Meee., (8888) 8, 888.
[75] Meeeeeee, M.; Meeeeeee, M., Meee. Mee. Mee., (8888) 88, 888.
[76] Meeeee, M. M.; Meeee, M., Meeeeeeeeee: Meeeeeeee, (8888) 88, 8888.

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