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Please login to access the full content or check if you have access via3.3 [m + n + 1]-Carbocyclization Reactions
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Shibata, T., Science of Synthesis: Stereoselective Synthesis, (2011) 3, 125.
General Introduction
Various types of stereoselective [m + n + 1] carbocyclizations have been reported. This chapter focuses on the carbonylative [2 + 2 + 1] reactions of enynes, namely the Pauson–Khand reaction, which yields synthetically important bicyclopentenones and has been comprehensively studied.[1] Other types of [m+n+1] carbocyclizations, including [3 + 2 + 1], [4 + 2 + 1], [5 + 2 + 1], and [4 + 4 + 1] reactions, are also mentioned, where the C1 source is carbon monoxide or (trimethylsilyl)diazomethane.
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References
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