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1.1.7.2.1.1 Arene Nucleophiles: Friedel–Crafts Processes

DOI: 10.1055/sos-SD-204-00129

MacMillan, D. W. C.; Watson, A. J. B.Science of Synthesis: Asymmetric Organocatalysis, (20121329.

Iminium-catalyzed enantioselective FriedelCrafts processes offer an expedient method for the installation of benzylic stereogenicity.[‌65‌] A range of aromatic species have been found to be effective nucleophiles in these processes including anilines, pyrroles, and indoles, generating libraries of synthetically useful structural motifs from readily available starting materials.

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