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Please login to access the full content or check if you have access via1.2.5.2 Palladium-Free Cross Coupling of Alkynylsilicon Derivatives
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DOI:
10.1055/sos-SD-207-00308
Chartoire, A.; Nolan, S. P., Science of Synthesis: Cross Coupling and Heck-Type Reactions, (2013) 1, 520.
Palladium is not always required for the cross couplings of alkynylsilicon derivatives. In such cases, the reaction is catalyzed by the presence of copper and is promoted either by a fluoride source or by polar solvents.