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DOI: 10.1055/sos-SD-207-00308

Chartoire, A.; Nolan, S. P.Science of Synthesis: Cross Coupling and Heck-Type Reactions, (20131520.

Palladium is not always required for the cross couplings of alkynylsilicon derivatives. In such cases, the reaction is catalyzed by the presence of copper and is promoted either by a fluoride source or by polar solvents.