Science of Synthesis

Pitaval, A.; Echavarren, A. M., Science of Synthesis: Cross Coupling and Heck-Type Reactions, (2013) 1, 527.

General Introduction

The Stille reaction of organostannanes with organic electrophiles is one of the most general and selective palladium-catalyzed cross-coupling reactions (‌Scheme 1‌).[‌1‌–‌5‌] The first examples were reported in the period 1976–1978 by Eaborn,[‌6‌] Kosugi,[‌7‌–‌9‌] and Stille,[‌10‌] which was immediately followed by systematic work by the group of Stille that established the scope and the basic aspects of the mechanism of this reaction.[‌11‌]

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References