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2.3.4 Vinyl- and Arylboronates as Key Components in Multicomponent Reactions

DOI: 10.1055/sos-SD-211-00113

Szabó, K. J.Science of Synthesis: Multicomponent Reactions, (20142369.

The synthesis of vinyl- and arylboronates is an area of wide spread interest in organic synthesis. The two most important methods are based on catalytic C—H and C—X (X = halogen) functionalization methodologies. These processes can be combined with other reactions in a one-pot sequence. The most important transformations of the in situ formed allyl- and vinylboronates involve Suzuki–Miyaura couplings,[‌4‌] but other transformations, such as the Chan–Lam reaction[‌10‌] and oxidation to phenols, have also been reported.

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