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1.1.4.1.4 Hydroformylation of Alkenes in Supercritical Carbon Dioxide

DOI: 10.1055/sos-SD-212-00096

Mortreux, A.; Sauthier, M.; Monflier, E.; Tilloy, S.Science of Synthesis: C-1 Building Blocks in Organic Synthesis, (20141176.

The hydroformylation of alkenes can be efficiently performed in supercritical carbon dioxide as the reaction medium.[‌33‌] Compared to classical solvents, supercritical gases (i) have high miscibility with reactant gases, (ii) do not show a liquid/gas phase boundary, (iii) have high diffusivity/low viscosity, and (iv) have high compressibility.

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