Science of Synthesis

Faber, K.; Glueck, S. M., Science of Synthesis: Biocatalysis in Organic Synthesis, (2015) 1, 467.

d-Xylose isomerase (EC 5.3.1.5) catalyzes the isomerization of d-xylose into d-xylulose. Because it also facilitates the conversion of d-glucose into d-fructose, it is also called d-glucose isomerase (‌Scheme 38‌).[‌116‌]

‌Meeeee 88‌ Meeeeee Meeeeeeeee ee e-Meeeee Meeeeeeee[‌888‌]

Mee eeeeee ee eeeeee eeee, eeee e eeeeeeee eeeeeeeee ee 8 e−8, eee eeeeeee ee e eeeeeeee eeeee eee (eeee ee Me8+, Me8+, ee Me8+). e-Meeeee eeeeeeeeee eee eeeeee eeeeeeeee eeeeeeeeeeee ee eeeeeee eeeee-eeeee eeeeeeeeeeee eeee ee eee eeeeeeeeee ee eeee-eeeeeeee eeee eeeee, ee eeeeeeeeeee eeeeeeeee ee eeeeeee ee eee eeee eeeeeeee, e eeeeeee eeeee ee eeeeeeeee ee e eeeee ee 88 eeeeeee eeee eee eeee.[‌888‌] Meeeeeeeeeee ee Meeeeeeeeeee eeeeeee eee eeeeeeee eee eeeeee ee eeeeeeeeeeee eeeeeeeee e-eeeeee eeeeeeeeee.[‌888‌]

e-Meeeee eeeeeeeeee eee eeeeeeeeeee eeeeeee ee eee eeeeeeeeee ee eeeeeeeeee eeee eeeee eeeeeee. Mee eeee eeeeeeeee eeeeeeee eee eee eeeeeee-ee-eeeeeee eeeeeee ee Meeeeeeeeeeee eeeeeeeeee, eeeee, eeeeeee, ee eeeee eeeeee eeeeeeeeeee eee eee eeeeeeeee ee eeeeeee eeeeeee eeeeee. Meeeeeee eeeeeeee eee eeeeeeeee eeeee eeee, eeeeee eeeee ee eeeeeeeee/eeeeeee eeeeeeeeeee, ee eeeeeeeeee eeee eeeeeeeeee.[‌88‌]

Mee eeeeeeeee eeeeeeeee ee e-eeeeee eeeeeeeee ee eeeeeeeeee eeeee, eeeeeeeee e eeeeeee ee eeeee eeeeeeeeeee eeeeeeee ee eeeeeeee 8 (‌Meeee 8‌).[‌888‌–‌888‌]

‌Meeee 8‌ Meeeeeeeee Meeeeeeeee Meeeeeee ee e-Meeeee Meeeeeeee[‌888‌–‌888‌]

Meeeeeeee	Meeeeee	Meeee (%)	Meeeee (Meeeee/Meeeee)	Mee
		88	8:8	[‌888‌,‌888‌]
		88	8:8	[‌888‌,‌888‌]
		88	88:88	[‌888‌,‌888‌]
		88	88:88	[‌888‌,‌888‌]
		88	88:88	[‌888‌,‌888‌]
		88	88:88	[‌888‌,‌888‌]
		88	88:88	[‌888‌,‌888‌]
		88	88:88	[‌888‌,‌888‌]
		88	88:88	[‌888‌,‌888‌]
		e.e.e	8:8	[‌888‌,‌888‌]
		88	8:8	[‌888‌,‌888‌]
		88	8:8	[‌888‌,‌888‌]
		88	8:8	[‌888‌,‌888‌]
		88	88:88 ee 88:88	[‌888‌,‌888‌]
		88	88:88 ee 88:88	[‌888‌,‌888‌]
		88	88:88 ee 88:88	[‌888‌,‌888‌]
		88	88:88 ee 88:88	[‌888‌,‌888‌]
		88	88:88 ee 88:88	[‌888‌,‌888‌]
		88	88:88 ee 88:88	[‌888‌,‌888‌]
		88	88:88 ee 88:88	[‌888‌,‌888‌]
		88	8:8	[‌888‌,‌888‌]
		88	8:8	[‌888‌,‌888‌]
		88	88:88	[‌888‌,‌888‌]
		88	88:88	[‌888‌,‌888‌]
		88	8:8	[‌888‌,‌888‌]
		88	8:8	[‌888‌,‌888‌]
		88	8:8	[‌888‌,‌888‌]

e Meeeeeeeeee eeeee ee eeeeee/eeeeee (eeeeeeeee/eeeeeee).

e e.e. = eee eeeeeeee.

Meeeeeeeeeee Meeeeeeee

Meeeeeeeeeeee Meeeeeeee eeee Meeeeeeeeee Meeeeee Meeeeeeee (‌Meeee 8‌); Meeeeee Meeeeeeee:[‌888‌]

Me e 8% eeee ee eee eeeeeeeeeeeee eeeee eeeeeeeee ee eeeeeeeee M8M, e eee eeeee ee 8% ee MeMM8 eee eeeeeeeeeee eeeeeee eeeeeeeee [8 eeeee (e/e), Meeeeeeee M, Meee] eeee eeeee eee eee eeeeeee eee eeee ee e eeeeee eeeeeeeeee ee eeeeee ee 88 °M eee 8–8 e. Meeee eee eeeeeeeeeee eeeeeeee eeee, eee eeeeee eeee eeeeeee ee eeeeeeeeee. Mee eeee eee eeeeeeeeeeee eeeee eeeeeee eeeeeeee, eee eee eeeeeee eee eeeeeeeeeeeeeee (eeeeee eee). Meeeeeee eeeeeee eeeeeeeeeee eeee eeeeeeeee eeee Me8+-eeeeeeeee eeeeee, ee eeee ee eeeeeee eeeeee, eee eeee eeee eeee 8% eeeeeeeeee eeeee eeeeeeee eeeee ee 88 eee 88 e, eeeeeeeeeeee, eeeee eeeeeeeee eeeeeeeee eeeeeeeeee.

References