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5.3.3.1 Palladium-Catalyzed Intramolecular Aminooxygenation

DOI: 10.1055/sos-SD-225-00172

Chemler, S. R.; Wdowik, T.Science of Synthesis: Catalytic Oxidation in Organic Synthesis, (20171381.

A new approach toward tetrahydrofuran derivatives 80 via an aminooxygenation process is based on palladium(II)/palladium(IV)-catalyzed transformations. The reaction involves 5-endo-trig oxypalladation and uses (diacetoxyiodo)benzene as oxidant (Scheme 30).[‌76‌]

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References


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