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16.1 [2 + 1] Cycloadditions

DOI: 10.1055/sos-SD-229-00260

Amador, A. G.; Scholz, S. O.; Skubi, K. L.; Yoon, T. P., Science of Synthesis: Photocatalysis in Organic Synthesis, (2018) 1, 467.

Investigations into visible-light photocatalytic [2 + 1] cycloadditions are limited, despite their potential to provide rapid access to synthetically valuable three-membered-ring moieties. This section will highlight robust methodologies for the visible-light photocatalytic generation of cyclopropane and aziridine products via cycloaddition of alkenes with carbenoids or nitrenes, respectively.


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