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2.4.4 Method 4: Synthesis of Tricarbonylmetal--Arene Complexes from Metal–Carbonyls

DOI: 10.1055/sos-SD-002-00214

Kündig, E. P.; Pache, S. H.Science of Synthesis, (20032159.

The (arene)tricarbonyl complexes of chromium, molybdenum, and tungsten are yellow to red, often crystalline compounds, which are stable to air in the solid state and can be stored for long periods, provided that they are kept out of light. In solution, they are moderately (chromium, tungsten) to strongly (molybdenum) air sensitive.