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2.4.7 Method 7: Synthesis of Optically Active Arene Complexes

DOI: 10.1055/sos-SD-002-00214

Kündig, E. P.; Pache, S. H.Science of Synthesis, (20032188.

The synthesis of optically active arene complexes has been developed only for chromiumarene complexes (for applications, see Section 2.4.10). Distinct categories in this class of compound are shown in Scheme 36. Chirality may be associated with (a) a stereogenic center in an aryl substituent, (b) a chiral ligand on the metal, (c) a stereogenic metal center, or (d) different ortho or meta arene substituents (planar chirality).

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