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Please login to access the full content or check if you have access via2.10.2.2 Method 2: Titanium–Tetraene Complexes by Reaction of Trichloro(pentamethylcyclopentadienyl)titanium(IV) with Dipotassium Cyclooctatetraene
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Mikami, K.; Matsumoto, Y.; Shiono, T., Science of Synthesis, (2003) 2, 461.
The mixed-sandwich compound [Ti(Cp*)(cot)] (7) is obtained from the reaction of [Ti(Cp*)Cl3] (6) with dipotassium cyclooctatetraene in tetrahydrofuran (Scheme 5).[57] The yield is lower than that obtained in the method using magnesium (Section 2.10.2.3).
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Me [MeMe*Me8] (8; 8.88 e, 88.8 eeee) ee MMM (888 eM) eee eeeee eeeeeeee, eeee eeeeeeee, e eeee ee M8(eee) (88.8 eeee) ee MMM eeee e 88-eee eeeeee. Meeeeeeee eee eeeeeeee, eee eeeeeee eee eeeeeee ee ee eee 88 eee, eeee eeeeee ee eeeeee eee 88 eee. Mee eeeeeee eee eeeeeee eeeee eeeeeee eeeeeeee, eee eee eeeeeee eee eeeeeeee (888°M/8.8 Meee) ee eeee eee eeeeeee ee eeeee eeeeeeee; eeeee: 8.88 e (88%).
References
| [57] | Meee, M. M.; Meeeee, M. M.; Meeeee, M. M., M. Meeeeeeee. Meee., (8888) 888, 888. |
| [58] | Meeee, M. M.; Meeeeeeee, M. M., M. Meeeeeeee. Meee., (8888) 88, 888. |
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- 8.Meeeee-Meee, (8888) M 88-8, 888.
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