0 Hits

  • Previous / Next

You are using Science Of Synthesis as a Guest.
Please login to access the full content or check if you have access via Method 6: Reaction between Tetraalkoxytitanium(IV) or Tetraamidotitanium(IV) ­Complexes and Cyclopentadienes

DOI: 10.1055/sos-SD-002-00576

Mikami, K.; Matsumoto, Y.; Shiono, T.Science of Synthesis, (20032494.

Tetrakis(dimethylamido)titanium(IV) reacts exothermally when treated with an excess of cyclopentadiene to give tris(dimethylamido)(η5-cyclopentadienyl)titanium(IV) (82, R1=Me) (Scheme 38).[‌185‌] The alkoxy complexes [TiCp*(Ot-Bu)3],[‌184‌] [Ti(η5-MeC5H4)(OEt)3],[‌184‌] and [Ti(η5-Ind)(OBu)3] (Ind=indenyl)[‌186‌] are also synthesized from the corresponding tetraalkoxytitanium(IV) complexes by this method.

Meeeee 88 Meee(eeeee)eeeeeeeeeeeeeeeeeeeeeeee(MM) Meeeeeeee eeee eee Meeeeeeeeeeee Meeeeeee(MM) Meeeee eee Meeeeeeeeeeeeee[‌888‌]