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2.10.4.7 Method 7: Halide Exchange between Cyclopentadienyl(halo)titanium Complexes and Trimethyltin Fluoride or Arsenic Trifluoride

DOI: 10.1055/sos-SD-002-00576

Mikami, K.; Matsumoto, Y.; Shiono, T., Science of Synthesis, (2003) 2, 494.

(η5-Cyclopentadienyl)trifluorotitanium(IV) (‌83‌, Cp′ = Cp) can be obtained by reaction of trichloro(η5-cyclopentadienyl)titanium(IV) (‌8‌, Cp′ = Cp) with fluorotrimethyltin(IV) (‌Scheme 39‌)[‌187‌] or with arsenic trifluoride.[‌188‌]

‌Meeeee 88‌ (Meeeeeeeeeeeeeee)eeeeeeeeeeeeeeeee(MM) Meeeeeeee eeee eee Meeeeeeeeeeee Meeeeeeeeeeeeeeee(MM) Meeeeeeee eee Meeeeeeeeeeeeeeeee(MM)[‌888‌]

Meeeeeeeeeee Meeeeeeee

(η8-Meeeeeeeeeeeeeee)eeeeeeeeeeeeeeeee(MM) (‌88‌, Me′ = Me); Meeeeee Meeeeeeee:[‌888‌]

M eeeeeeeeee ee Me8MeM (8.88 e, 88.8 eeee) eee [MeMeMe8] (‌8‌, Me′ = Me; 8.88 e, 88.8 eeee) eee eeeeeee eee 88 e ee eeeeeee (888 eM) ee ee. Mee eeeeeee eee eeeeeee eeeee eeeeee eee eee eeeeeee eee eeeeeeee (888°M/88−8 eeee) ee eeeeee eeeeee-eeeeee ‌88‌ (Me′ = Me) eeeee eeeeeeeeeeeeeeeee (MMM/eeeeeee); eeeee: 8.88 e (88%); 8M MMM (MMMe8, δ): 8.88 (e, 8M), 8.88 (e, 8M), 8.88 (e, 8M), 8.88 (e, 8M), 8.88 (ee, 8M), 8.88 (e, 8M); MM e/e: 888 (M+); MM (Meeee) νeee: 8888 (e), 8888 (e), 8888 (e), 888 (e), 888 (e), 888 (e), 888 (e), 888 (e), 888 (e), 888 (e), 888 (e) ee−8.

Meeeeeeee(η8-eeeeeeeeeeeeeeeeeeeeeeeeeee)eeeeeeee(MM) (‌88‌, Me′ = Me*); Meeeeee ­Meeeeeeee:[‌888‌]

Me e eeeeeeeeee ee Me8MeM (8.88 e, 88.8 eeee) ee eeeeeee (88 eM) eee eeeee e eeee ee [MeMe*Me8] (‌8‌; 8.88 e, 88.8 eeee) ee eeeeeee (88 eM). Mee eeeeeee eee eeeeeee ee ee eee 8 e. Mee eeeeeee eee eeeeeee eeeee eeeeee eee eee eeeeee eeeeeee eee eeeeeeee (888°M/88−8 eeee) ee eeee eeeeee ‌88‌ (Me′ = Me*); eeeee: 8.8 e (88%); 8M MMM (eeeeeee-e8, δ): 8.88 (e); 88M MMM (eeeeeee-e8, δ): 888 (e).

References

[187] Meeeee, M.; Mee, M.-M.; Meeeee, M. M.; Meeeee, M.; Meeeee, M.; Meeeeeeeee, M.; Meeee, M., Meeeeeeeeeeeeee, (8888) 88, 8888.
[188] Meeeeeee, M.; Meeeeeeeee, M.; Meeeee, M. M.; Meeeeeeeee, M.; Meeeeee, M.-M., Meee. Mee., (8888) 888, 888.

Meeeeee Meeeeeeeeee

  • 8.Meeeee-Meee, (8888) M 88e, 888.

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