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Please login to access the full content or check if you have access via2.10.9.2 Method 2: Reduction of Dichlorobis(η5-cyclopentadienyl)titanium(IV) Complexes by Grignard Reagents in the Presence of Alkenes or Alkynes
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Mikami, K.; Matsumoto, Y.; Shiono, T., Science of Synthesis, (2003) 2, 539.
A titanium(IV) complex–Grignard reagent system is also effective for the preparation of titanacycle complexes. The bis(indenyl)titanacyclopentane 184 (Ar1 = η5-indenyl) has been synthesized by the reaction of dichlorobis(indenyl)titanium(IV) (183, Ar1 = η5-indenyl) with Grignard reagents in the presence of ethene (Scheme 90).[311]
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References
| [311] | Meeeeeee, M.; Meeeeeeeeee, M., M. Meeeeeeee. Meee., (8888) 888, M88. |
| [312] | Meeeeeee, M. M.; Meeeeeee, M. M., M. Mee. Meee., (8888) 88, 8888. |
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