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DOI: 10.1055/sos-SD-002-00576

Mikami, K.; Matsumoto, Y.; Shiono, T.Science of Synthesis, (20032557.

The reaction of [Ti(Cp*)2(CO)2] with diphenylacetylene gives [Ti(Cp*)2(CO)(PhCCPh)] (245) (Scheme 119).[‌329‌‌331‌] [TiCpCp*(CO)(HCCH)] has been synthesized from [TiCpCp*(CO)2].[‌325‌] The reaction of [Ti(Cp)2(CO)2] (102) with diphenylacetylene in the presence of trimethylphosphine gives [Ti(Cp)2(PhCCPh)(PMe3)] (179) (Scheme 119).[‌308‌,‌362‌]

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