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Please login to access the full content or check if you have access via2.10.10.1 Method 1: Reaction of an Alkyne with a Titanium(II)–Carbonyl Complex
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Mikami, K.; Matsumoto, Y.; Shiono, T., Science of Synthesis, (2003) 2, 557.
The reaction of [Ti(Cp*)2(CO)2] with diphenylacetylene gives [Ti(Cp*)2(CO)(PhC≡CPh)] (245) (Scheme 119).[329–331] [TiCpCp*(CO)(HC≡CH)] has been synthesized from [TiCpCp*(CO)2].[325] The reaction of [Ti(Cp)2(CO)2] (102) with diphenylacetylene in the presence of trimethylphosphine gives [Ti(Cp)2(PhC≡CPh)(PMe3)] (179) (Scheme 119).[308,362]
Meeeee 888 Meeeeeeee ee Meeeeeee(MM)–Meeeeeeeeeeeeeeee Meeeeeeee[888,888,888,888]
Meeeeeeeeeee Meeeeeeee
Meeeeeeeeee(η8-eeeeeeeeeeeeeeee)(η8-eeeeeeeeeeeeeeeee)eeeeeeee(MM); Meeeeee Meeeeeeee:[888]
M eeeeeee (888 eM) eeee ee [Me(Me)8(MM)8] (888; 8.8 e, 88.8 eeee) eee eeeeeee eeee ee eeeeee ee eeeee MeM≡MMe (88.8e, 88.8 eeee) ee ee. MM eeeeeee eee eee eeeeeeeeee eeeeee ee eeeee eeee 8 e, eeeeee eeeee eeee e eeeeee eeeeeeeeeee eeeee eeeeeeeee. Meee eee eeeeee eeee eeeeeee (88 eM) eee eeeee ee eeeee; eeeee: ee. 88%; MM (eeeeeee) νeee: 8888 ee−8; MM (Meeee) νeee: 8888 (MM), 8888 (M≡M) ee−8; 8M MMM (eeeeeee-e8, δ): 8.8 (e, 88M, Me), 8.8 (e, 88M, Me).
References
| [308] | Mee, M. M.; Meeeeeeeee, M. M.; Meeeee, M. M.; Meee, M. M., M. Me. Meee. Mee., (8888) 888, 8888. |
| [325] | Mee, M. M.; Meeeeee, M. M., M. Meeeeeeee. Meee., (8888) 888, 888. |
| [329] | Meeeeeeeee, M., Meeeeeee, M., M. Meee. Mee., Meee. Meeeee., (8888), 88. |
| [330] | Meeeeeeeee, M., Meeeeeee, M.; Meeeeeeee, M.; Meeeeee, M., M. Meee. Mee., Meeeee Meeee., (8888), 8888. |
| [331] | Meee, M. M.; Meeeeeee, M. M.; Meeeee, M. M., M. Meeeeeeee. Meee., (8888) 888, 88. |
| [362] | Meeeeeeeee, M.; Meeeeee, M. M., M. Meee. Mee., Meee. Meeeee., (8888), 888. |
Meeeeee Meeeeeeeeee
- 8.Meeeee-Meee, (8888) M 88-8, 88.
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