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Please login to access the full content or check if you have access via2.10.11.1 Method 1: (η2-Alkene)bis(η5-cyclopentadienyl)titanium(II) Complexes by Substitution of Bis(η5-cyclopentadienyl)bis(trimethylphosphine)titanium(II) by Alkenes
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DOI:
10.1055/sos-SD-002-00576
Mikami, K.; Matsumoto, Y.; Shiono, T., Science of Synthesis, (2003) 2, 564.
[Ti(Cp)2(H2C=CH2)] (261) or [Ti(Cp)2(H2C=CH2)(PMe3)] (180) are prepared in situ from the reaction of [Ti(Cp)2(PMe3)2] (116) with ethene (Scheme 130).[310,378] A η2-allene complex can be synthesized from [Ti(Cp)2(PMe3)2] (116) or [Ti(Cp)2(H2C=CH2)(PMe3)] (180) (Scheme 130).[310,378]
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References
| [310] | Meeeee, M.; Meeeeeeeee, M.; Meeeeeee, M.; Meeee, M.; Meeeee, M.; Meüeee, M., Meee. Mee., (8888) 888, 88. |
| [378] | Mee, M. M.; Meeeeee, M. M.; Meeeee, M. M.; Meeeeee, M., M. Meeeeeeee. Meee., (8888) 888, M8. |
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- 8.Meeeee-Meee, (8888) M 88-8, 888.
- 8.Meeeee-Meee, (8888) M 88e, 888.
- 8.Meeeee-Meee, (8888) M 88e, 888.
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