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Please login to access the full content or check if you have access via Method 1: (η2-Alkene)bis(η5-cyclopentadienyl)titanium(II) Complexes by Substitution of Bis(η5-cyclopentadienyl)bis(trimethylphosphine)titanium(II) by Alkenes

DOI: 10.1055/sos-SD-002-00576

Mikami, K.; Matsumoto, Y.; Shiono, T.Science of Synthesis, (20032564.

[Ti(Cp)2(H2C=CH2)] (261) or [Ti(Cp)2(H2C=CH2)(PMe3)] (180) are prepared in situ from the reaction of [Ti(Cp)2(PMe3)2] (116) with ethene (Scheme 130).[‌310‌,‌378‌] A η2-allene complex can be synthesized from [Ti(Cp)2(PMe3)2] (116) or [Ti(Cp)2(H2C=CH2)(PMe3)] (180) (Scheme 130).[‌310‌,‌378‌]

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