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Please login to access the full content or check if you have access via3.4.7.4 Method 4: From Alkenyllithium Reagents
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DOI:
10.1055/sos-SD-003-00274
Heaney, H.; Christie, S., Science of Synthesis, (2004) 3, 613.
The use of alkenyllithium reagents is one of the most common for the preparation of alkenylcuprates. In general, the cuprate is prepared by the addition of 2 equivalents of the alkenyllithium reagent to a copper source, commonly a copper(I) halide, at low temperature in an ethereal solvent. The cuprate is then used in a subsequent reaction.
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